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    • 专利摘要:
    APPARATUS AND METHOD FOR LEATHER PRINTING. It is a device for printing on leather that includes an ink acceptor applicator that applies ink directly to a leather surface; an ink applicator that applies ink to the ink acceptor and / or the leather surface; an additive applicator that applies additive to the paint acceptor, the paint and / or the leather surface; a barrier that has a surface configured to contact the acceptor, the ink and the additive on the leather surface; and a heater that heats the barrier surface to a predetermined temperature or to a temperature in a selected temperature range in such a way that the barrier, which is substantially impermeable to paint and has a melting point above the selected temperature range , contact at least the acceptor ink and the additive on the surface directly in order to liquefy the acceptor ink and the additive on the leather and the acceptor, the ink and the additive fuse and penetrate the leather.
    公开号:BR112014022643B1
    申请号:R112014022643-1
    申请日:2013-03-14
    公开日:2021-01-05
    发明作者:Pantelis Yiannakou
    申请人:Codus Holdings Limited；
    IPC主号:
    专利说明:

    RELATED ORDER
    [001] This is a non-provisional order for Order No. US 61 / 610,531 filed on March 14, 2012, the subject matter of which is incorporated as a reference. TECHNICAL FIELD
    [002] This disclosure refers, in general, to apparatus for printing on leather, methods of printing on leather, computer programs and computer systems to carry out such methods. BACKGROUND
    [003] Leather is manufactured and finished on a commercial scale in tanneries. There are several different methods of tanning leather. Two main variants are chrome and vegetable tanning. The leather is usually colored by dyeing. Various finishes can be applied such as embossing or polishing. These methods try to add some pattern, texture and depth to the surface, but have limited impact.
    [004] Printing on leather can be difficult as the ink generally does not bond well to a complex, organic, non-uniform substrate, such as leather. In addition, printing on leather is difficult due to non-uniform surface properties, for example, shape, color, density, content (eg water, proteins, fat, oils and / or varnish), concentration of pore, leveling, thickness and surface roughness. Different regions of a skin can have different properties due to differences in exposure to the sun. In this way, there is a probability of having significant variation in a single skin as well as between skins in a batch. Leather printing techniques can suppress at least one common leather property, for example, flexibility, surface roughness, appearance, sensation (to the human touch), breathability and / or absorption. One of the desirable characteristics of leather is flexibility. It is normally used in places where it is necessary to bend and flex (for example, shoes, seats, accessories, etc.). Printing on the leather surface is disadvantageous if the ink is weakly bonded and thus easily removed during depreciation by normal use, or if the printing cracks when flexed.
    [005] Additional difficulties can be found in printing on leather with the use of printing techniques known in other fields of the technique that involve printing on non-leather substrates if the ink molecules do not bond well with the leather. For example, printing on leather using printing techniques most commonly applied to paper can result in only a few ink molecules bonding to the leather so that the printed color / pattern is irregular and / or fainted . Such coloring / patterning merely printed on a leather surface can wear out easily, quickly and / or irregularly and / or have low light resistance and, therefore, may not be durable.
    [006] There remains a need for a method of coloring or patterning leather through printing in a way that minimizes deterioration of at least one leather property and, preferably, has advantages such as, among others, durability, coloring / high definition standardization, good resistance to heat-induced damage / deformation (eg reduced crack), low color transfer in wet conditions (ie, low color / ink dye displacement when wet), low cost and / or efficient (for example, faster). Given the volumes of leather produced and finished each year, there is also a need for an industrial leather printing process suited to the operable purpose in the harsh environment of a tannery or finishing plant.
    [007] The following disclosures are referred to: Document No. GB2379188A; Document WO / 2006/129604; and Document no WO / 01/32434, for additional background. BRIEF DESCRIPTION OF THE DRAWINGS
    [008] For a better understanding and to show how the process can be carried out, reference will now be made, by way of example, to the attached drawings, in which:
    [009] Figure 1 shows, schematically, a reverse stretch drum used in a post-tanning stage, pre-storage stage of the process described in detail below, to tighten the leather surface structure, opening the structure poster.
    [0010] Figure 2 shows, schematically, a storage / dehydration unit.
    [0011] Figure 3 shows, schematically, a pre-press table.
    [0012] Figure 4 shows, in a schematic way, a scanning table.
    [0013] Figure 5 shows, schematically, a printing step that may involve: (1) Sheet / barrier brought to the substrate surface; (2) Vacuum from below seals the substrate; (3) pressurizer applies heat and pressure; (4) without Vacuum, press cursor rises, sheet rises and is laminated to clean up fragment, substrate moves.
    [0014] Figure 6 shows, schematically, a cross section of the printer.
    [0015] Figure 7 is a flow diagram of RIP and process control.
    [0016] Figure 8 is a table of possible specifications selected.
    [0017] Figure 9 shows a schematic of an example of a selected process.
    [0018] Figures 10 (a) and 10 (b) show graphs of variation in success and failure rates with temperature.
    [0019] Figures 11 (a) and 11 (b) show photographs of test results classified as (a) failure (b) success.
    [0020] Figure 12 shows, schematically, a leather surface, in which the lines represent the fibrous / porous nature of the substrate.
    [0021] Figure 13 is a cross-sectional micrograph of a leather substrate.
    [0022] Figure 14 shows, schematically, ink deposited on the surface of the substrate shown in Figure 12.
    [0023] Figure 15 shows, schematically, a very thin layer of additive deposited on the paint and surface of the substrate of Figure 14.
    [0024] Figure 16 is a microphotograph of the surface of a leather substrate.
    [0025] Figure 17 shows, schematically, the leather / paint / additive pressed with heat and pressure for a predetermined time.
    [0026] Figure 18 shows, schematically, that heat softens the layer of paint and additive, which then penetrates the surface of the leather through capillary action.
    [0027] Figure 19 is a photomicrograph of a cross section of printed leather. SUMMARY
    [0028] A device for printing on leather is provided including a device that applies an ink acceptor base coat directly to a prepared leather surface, an ink applicator that applies ink to the base coat and / or the surface of the leather, an additive applicator that applies the additive directly to the base coat, paint on the surface of the leather and / or the surface of the leather, a barrier that has a surface configured to contact at least with the additive and paint on the leather surface, and a heater that heats the barrier surface to a predetermined temperature or a temperature within a predetermined temperature range so that the barrier, which is substantially impermeable to the paint and has a melting point higher than the predetermined temperature range, comes in contact with the additive and paint on the surface directly to soften the additive and paint on the leather and the additive and paint penetrates the co uro.
    [0029] Leather printing methods are also provided including applying an ink acceptor base coat directly to a leather surface, applying ink to the base coat and leather surface, applying an additive to the coating the ink acceptor, the ink and the leather surface, heat a barrier surface that is substantially impermeable to the ink to a predetermined temperature or a temperature within a predetermined temperature range, and come into contact with the heated barrier which has a higher melting point than the predetermined temperature range with at least the additive and paint on the surface directly to soften the applied additive and paint so that the paint penetrates the leather.
    [0030] Computer programs that perform printing methods in conjunction with the device are also provided.
    [0031] Computer systems are additionally provided that include an input that inserts the measurements of the surface properties of a piece of leather, an output that emits the scan results, data memory that stores the inserted measurements, a code program memory storage processor control, and a processor coupled to input, output, data memory, and program memory that loads and deploys the processor control code, where the code, when executed implemented, deploys printing methods. DETAILED DESCRIPTION
    [0032] It will be verified that the following description is intended to refer to specific examples of structure selected for illustration in the drawings and is not intended to define or limit the disclosure, with the exception of the attached claims.
    [0033] A device for printing on leather is provided. The apparatus may include an ink acceptor applicator configured to apply an ink acceptor base coat directly to the leather surface, an ink applicator configured to apply ink directly to the base coat and / or the leather surface. ; an additive applicator configured to apply additives to the base coat, paint and / or leather surface; a heated press configured to heat the surface to a predetermined temperature or a temperature within a predetermined temperature range, the additive configured to contact the paint on the surface directly to soften and coat the leather so that the acceptor is applied and additive-coated paint penetrates the leather, with the additive forming a protective coating for the paint.
    [0034] The device can be configured as a platform, roll printer or similar. A roll configuration may be faster, but there may be some misalignment due to relative roller movements on each side of the leather. Printing may involve coloring and / or patterning the leather. The "inside" impression of the leather means that the ink enters the leather. The ink applicator can be one or more ink heads, which can be controlled digitally. Additionally or alternatively, the paint can first be applied to the additive and then to the leather so that the additive acts at least as part of the paint applicator. The paint acceptor can be a polyamide such as NYLON, preferably a NYLON 6, 12 aqueous suspension mixture; NYLON 12 and NYLON 6, 10 and can be sprayed as a powder or as a liquid such as a suspension. The additive may be a polyamide such as NYLON, for example, similar or identical to the paint acceptor, and may be sprinkled in powder form, as a liquid such as a suspension or may be on a dry blade.
    [0035] Processes are also provided such as a representative process that includes the following steps 1 to 5: 1. Apply an ink acceptor base coat; 2. Put paint in a selected position on a prepared porous substrate; 3. Coat with a thin layer of additive; 4. Heat quickly (just like in a few seconds) (not necessarily with some pressure, just enough to keep the additive / paint in place); and 5. Make the paint, paint and additive acceptor soften and penetrate the leather surface and fill the pores through capillary action, in this way the paint is retained in the paint and additive acceptor and bonded to the leather.
    [0036] Advantageously, the polyamide used in both the top coat of the base coat and the thickness used can be such that while it protects and bonds the ink to the leather, it does not inhibit essential characteristics of the leather.
    [0037] Penetration into leather can be at a depth of at least about 0.0001 to 0.0040 mm below the surface, for example.
    [0038] The lowest temperature in a predetermined temperature range can be greater than about 100 ° C. Additionally or alternatively, the highest temperature in the predetermined temperature range can be less than about 220 ° C.
    [0039] The device may include a pressurizer configured to apply pressure directly to the applied acceptor, additive and paint by pressing a heated barrier against the applied paint, preferably where the pressure is a predetermined pressure or is within a pressure range predetermined. The pressure can be a pressure of less than about 0.34 MPa (50 psi), preferably more than about 0 psi. The pressurizer can comprise the thermal press with a non-fixed barrier. The apparatus can be configured to apply the heated barrier to the applied acceptor, paint and additive for a period of time within a predetermined time range or for a predetermined time period. The length of time can be less than or equal to about 2 minutes. The device can be configured to apply the heated barrier several times.
    [0040] The apparatus can be configured to dehydrate the leather by heating the leather to cause at least a portion of the leather's water content to become steam, and comprising at least one of: a vacuum suction unit for sucking the steam away from the leather; and an absorption unit to absorb steam away from the leather. Such dehydration can be used as, for example, preparation before printing or at the same time as the press during printing. Otherwise, the water comes out like steam and can interfere with the impression. Additionally or alternatively, some chemical pre-treatment of the leather may be carried out before printing.
    [0041] The apparatus may comprise a scanner which determines the spatial variation of at least one property of the leather, in which at least one property comprises liquid, protein and / or fat content, thickness, acidity, pore concentration, leveling, thickness, color and / or surface roughness. The sweeper is preferably additionally configured to detect a leather flaw. Additionally or alternatively, the size and / or shape of the leather can be scanned. The liquid can be, for example, water, oil, fat or the like. The acidity can be measured as a pH value.
    [0042] The device can include a printer that prints on leather, the printer comprising an adjuster that adjusts a total volume of ink applied to a point or location of the leather, and / or size and / or color of an ink droplet the adjustment to be deposited on the leather, the adjustment is dependent on a result of the determination of spatial variation of at least one property of the leather. The adjuster can be configured to increase the ink droplet size and / or the total volume of ink in a region of the leather that has greater damage or water content than that of a region neighboring the leather. The printer can be a roller or platform printer or, and preferably provides digitally controlled ink droplet deposition.
    [0043] The barrier and thermal press can be configured, preferably indented, to keep the paint substantially in a fixed position during the application of heat.
    [0044] Leather printing methods may include applying ink acceptor directly to a leather surface; apply paint to the coated leather surface, apply an additive to the paint; heating a barrier surface to a predetermined temperature or a temperature within a predetermined temperature range; contact the heated barrier with the ink, ink and additive acceptor on the surface directly to soften the acceptor, ink and additive in the leather so that the applied ink penetrates the leather, the barrier being substantially impermeable to the acceptor , paint and additive and has a melting point greater than the predetermined temperature range.
    [0045] The method can also include mechanically treating the skin before applying the paint, preferably indenting the leather to keep the paint substantially in a fixed position during application of additive and heat.
    [0046] Computer programs to perform the above method are also provided, as well as computer systems that include an input that inserts measurements of the surface properties of a piece of leather; an output that outputs scan results; data memory that stores the inserted measurements; a program memory storage processor control code; and a processor coupled to the input, output, data memory and program memory that loads and deploys the processor control code, the code comprising code to, when executed, implement the above method.
    [0047] It is evident that any amount of all the above aspects can be combined in any permutation.
    [0048] The following describes processes and concepts applicable to industrial leather printing machines. In addition, the following description refers to leather substrates to be printed on it. However, what follows is additionally applicable to printing on another non-leather material. In addition, the methods and apparatus of the present invention can be suitable for both vegetable-tanned leather and chrome-tanned leather.
    [0049] Experiments on printing ink on leather have shown that a selected combination of pressure, temperature and / or time is sometimes necessary. The acceptor and the thickness of the acceptor is also a variable. The additive and the thickness of the additive is also a variable. When at least one of these properties is increased above a selected value, the amount of ink entering the leather increases rapidly. This suggests that the ink enters the leather through capillary action: if the acceptor, ink and additive is pressed on the leather by a barrier (for example, a metal, ceramic plate, sheet and / or paper) impermeable to acceptor, paint and additive, so there may be substantially nowhere else for the combined liquid to be transferred except into the leather, which in relation to the liquid is porous in relation to the barrier. This was confirmed by electron microscope images that show that the printed ink is found on the leather below the surface of the leather as shown in Figure 18.
    [0050] The ink is printed more permanently than if it were found merely on the surface of the leather. The barrier can be arranged to receive the additive and paint before the leather and / or plate is moved laterally to face each other ready to apply the additive and paint to the leather. Alternatively, the plate that has the additive and paint on one side (for example, one side pointing upwards) can be rotated so that that side faces the leather (for example, the side then points so) downward towards the leather). The barrier can comprise a solid plate of any desired thickness.
    [0051] Additionally, the barrier may comprise a layer or metallic foil for direct contact with the leather. Such a layer of ceramic, sheet or paper can be supplied on a belt configured to rotate around drums so that the additive and paint can be applied to one side of the barrier configuration before that side is rotated to face for coated leather for applying paint to leather. It is possible to use transfer medium to apply additive and ink to the leather.
    [0052] The dependence on temperature and successful printing time confirms that the capillary action appears to occur as described above and that the diffusion of ink acceptor, additive liquid and ink can therefore be a dominant process for entering the ink in the leather. The transfer medium can be standard heat transfer paper (which comprises two-layer plastic, a polymer and a thin polyamide additive) as an ink carrier, ink based on standard HP pigment and set pressure at a constant from about 0 to about 0.34 MPa (50 psi) to print about 50 3 mm thick slices of uncooked perforated vegetable leather with an area of about 10 cm x 10 cm.
    [0053] Various combinations of temperature and times at the same pressure were tested. Figures 10 (a) and 10 (b) show how success rates (1 in Figure 10a) and failure (0 in Figure 10a) varied with temperature. Success was achieved when the transfer of paint into the leather occurred through the leather sample with good penetration. In unsuccessful tests, there was no transfer of paint inside the leather (ie, there was no penetration), an indefinite / unclear result (eg, non-uniform penetration), or damage (eg, drying, wrinkling and / or deformation of the leather, usually due to excessive heat and / or excessive time).
    [0054] Of interest, the additive and ink in successful cases penetrated the leather, filling the pores, instead of merely remaining on the surface of the leather. In addition, temperature and time were very determinants of success, both associated with functions substantially in the success rate stage as a function of temperature or time in a similar manner as shown in Figures 10 (a) and 10 (b). Thus, in these tests, almost no partial penetration was seen. Images of test results are shown in Figure 11 (a): failure and 11 (b): success. The cross sections of printed leather were examined using a very powerful microscope. The additive and paint was clearly seen to be "inside" the surface as opposed to "on" the surface, that is, penetrate to a depth of at least about 0.002 mm, in several cases, for example, micrometers.
    [0055] The following describes a mechanism that can occur and that can be described as "forced penetration". The resulting printing effect can be called a "digital tattoo", as the ink is embedded inside the surface of the substrate.
    [0056] A properly prepared substrate with a polyamide ink acceptor coating is presented for printing as shown in Figure 12. The substrate can be supported by a base with holes to allow a vacuum to be applied. The vacuum holds the substrate in place and removes excess water vapor that can inhibit printing. The lines show the "fibrous" nature of leather, which is a factor in many of the useful characteristics of leather. However, all drawings in this document are purely for the purpose of assisting understanding, that is, they are diagrammatic and, therefore, are not limited to specific relative dimensions or components.
    [0057] Figure 13 shows the internal leather structure in a great magnification. The ink droplets are deposited on the substrate to form the desired image shown in Figure 14. The ink droplets do not initially penetrate the leather, but instead remain on the surface, held in place by the ink acceptor. The ink can be deposited using various methods, depending on the desired image definition.
    [0058] A very thin layer of additive such as a polyamide is deposited on the surface, covering the deposited ink and any area covered by non-ink in Figure 15. The ink acceptor can be applied as a powder or in a liquid suspension . The additive can be sprayed as a powder or it can be deposited in a liquid form. The paint acceptor coating can be very thin, typically less than 0.0050 mm. The additive coating can be very thin, typically less than 0.0050 mm.
    [0059] The internal composition of the polyamide of both the paint acceptor and the additive is preferably similar to the internal composition of the leather as shown in Figure 16. It is a "series" of long chains and means that both leather and polyamide have characteristics similar characteristics, that is, flexibility, porosity, absorption, resistance and the like.
    [0060] The acceptor, ink and additive can then be thermally pressed using a press slide or a non-fixed barrier and then a press slide as shown in Figure 17. As a result, heat softens the acceptor, paint and additive, which then penetrates the porous surface of the substrate while substantially remaining in position. Although a metal press slide as the barrier is sufficient for heat transfer, it is preferable that the heat and pressure are conferred on the acceptor, ink and additive on the substrate surface quickly and without lateral movement, particularly if the printing is applied at industrial speeds. Before heat press, the paint on the surface is preferably in a dry (solid) state. When heat and pressure are applied, the acceptor, paint and additive soften quickly and then mix. The pressure from the barrier, in addition to capillary action, causes the mixture of acceptor, paint and additive to penetrate the porous substrate. Substantially, the paint does not spread as there is an impermeable barrier above and substantially equal pressure from the sides. Then, the acceptor, ink and additive diffuse directly downwards in the position that was placed on the surface.
    [0061] As shown in Figure 18, when the solid acceptor, paint and additive is exposed to heat and pressure, it seems to soften and penetrate. It can be held in position by the barrier in the form of a sheet under pressure from a press slide. The pressure differential across the leather can be increased by a vacuum applied from the base of the leather. Such a vacuum can also remove steam generated from the water on the leather. The acceptor, ink and additive hardens on the leather and the heat can "fix" the ink so that it bonds with the leather material. In this way, "forced penetration" can occur. Heat and pressure can be applied multiple times to further soften and fix the mixture.
    [0062] For the process to work effectively, several factors must be satisfied simultaneously. The leather must be prepared in the correct way, and the leather surface must be open (unfinished). The paint acceptor must be applied in the correct thickness. The paint must be of an appropriate composition. The additive must be correct so that, when in liquid form, together with the acceptor and ink, it is of sufficient viscosity to penetrate the leather. Pressure, temperature and time are also important to obtain a stable, robust result.
    [0063] Figure 19 shows a cross section in great magnification of a piece of printed leather. The top layer (dark) is about 0.0030 mm thick. It is the acceptor, ink and additive after softening and penetrating into the leather. "Stripes" from the mixture of acceptor, paint and additive filled the pores.
    [0064] The substrate, for example, leather is preferably presented in a favorable condition to accept the paint. This means that the leather is preferably porous to the favorable degree (preferably the fibers of the leather are also clear). The surface is preferably "narrow" as the thin surface structure will allow for more definite printing. As mentioned above, the water content is an additional consideration, as the process generates steam in the leather that can prevent printing. Other factors such as pH level, fat content, color and the like can similarly have an impact on the final print quality. In general, the finished leather will not be porous to the degree required for the forced penetration above to occur (although some finished leathers may be). "Finished" may mean, for example, that a protective coating has been applied, impermeable to the stain, waterproof, dyed by color, embossed in high grained relief, impermeable to water and / or with fire retardation. Thus, it may be preferable for the leather to be prepared in a certain way, for example, omitting certain finishing steps before the printing process is applied, for example, not tanned by certain dyeings. Thus, preferably, the tanned leather is unfinished and not dyed and has not been subjected to mechanical treatments of uniformity, sanding, polishing or, otherwise, resurfacing the surface and may interfere with the pore structure of the leather. However, the curing process can be modified to improve the printing capacity of the leather through mechanical, chemical and / or biological treatments such as through a tanning additive, for example, oxalic acid or hydride. sodium to whiten or lighten the color, inverse mechanical stretching over the shallow drums to open the pores, and / or dry in a heated jet of CO2 to open the pores.
    [0065] The ink is preferably of a type, for example, HPP (pigmented with high performance), or a flexible UV cured ink preferably with selected properties such as molecule size <1.0 μm and ink volume concentration> 20 %. The levels of lubricants and resins can be controlled for different types of leather. Good results have been achieved with the use of pigment-based paints. In this regard, the penetration temperature and the size of the pigment molecule are preferably adjusted for optimized printing.
    [0066] The ink is preferably placed on the leather with the use of known inkjet technology. There are at least two options for placing the paint. First, the paint can be placed directly on the prepared coated substrate. The paint acceptor is applied to the substrate before the paint is placed so that the paint is kept in place. Such an ink acceptor can reduce image blur. Alternatively or additionally, the ink can be applied to the barrier which may have ink drop "retainers", for example, small undulations on the barrier surface; for example, the barrier can be nano-built to have a matte texture suitable to hold the paint in place and / or the leather can be indented, for example, to rough the leather surface to reduce the mobility of the paint on the surface leather. Such indentation can be accomplished by moving a roll that has a wavy surface on the surface of the leather (for example, engraving in a cylinder a very fine pattern of recesses on the surface of the leather, for example, at a density of 10k ipis = about 600dpi so that it gets a uniform matte finish.) Such embossing can be done at around 120 ° C, for example, which can reduce the water content of the leather. In addition, such a cylinder engraving can substantially correct variations in leather thickness. Preferably, indentations are non-permanent deformations of the leather surface, for example, the leather naturally returns to its original non-indented state after, for example, a few seconds or minutes.
    [0067] Regarding the control and placement of the ink, in which the inkjet printing is used in an example, the ink droplets are placed in contact with the substrate in the exact position where the "injection" inside of the surface is required. The surface is ideally in the condition of accepting the paint. This may require specific surface preparation (mechanical and / or chemical). Ink droplet sizes and / or colors can also be adjusted according to color variations across the substrate. The frequent occurrence of leather flaws is also preferentially considered when placing the image.
    [0068] In view of the above, the process can be considered more similar to tattooing than conventional printing so that color management is not standard. The substrate may have properties that other conventionally printed substrates do not: non-uniformity of color and other characteristics, prevalence of surface flaws and the like. The preparation of the substrate surface improves the acceptance of color and ink management preferably assists in overcoming specific leather problems. With regard, more specifically, to printing, the parameters to be considered are temperature, time and pressure. The control of these parameters can take into account conflicting factors. The penetration and fixation of the acceptor, paint and additive is preferably achieved through heat and pressure. However, these two parameters can, in some circumstances, impact the characteristics of the substrate and, ultimately, even permanently damage the substrate. Ideally, therefore, minimum heat and / or minimum pressure are applied for a minimum time to achieve forced penetration and fix the paint to produce a stable red image without degrading the qualities of the leather. Each type of leather can have a different set of desired parameters, which can be sensitive to thickness and which can range from, for example, about 0.4 mm (binding) to, for example, about 8 mm (uses heavy industry), that is, variation by a factor of x20.
    [0069] Additional consideration can be given to the production of steam since the leather has a high water content that can turn into steam under heat and pressure and rise through the substrate and prevent the ink that may be trying to diffuse through the leather in the opposite direction. The impact of this effect can be reduced by presenting the substrate in a selected condition, for example, dehydrating the substrate and using a mechanical process (for example, vacuum removal of steam) during printing. Measurement and analysis of each individual piece of substrate to be printed, before printing, can be used to determine the desired parameters such as ink droplet size, color, heat pressure, time. For example, printing on 6 mm thick vegetable-tanned leather, perforated for use in saddles may involve different parameters when compared to goatskin, soft, thin 1.5 mm for gloves or upholstery leather or shoe leather.
    [0070] Post-printing, conditioning of the printed leather can be performed. Having made several mechanical and / or chemical adjustments to the leather as detailed above, and having exposed the leather to heat and pressure, the leather may not be in an ideal condition to continue through a finishing process line. The corrective mechanical and chemical processes such as rehydration, greasing, rolling and the like, therefore, can be applied to bring the leather to a suitable condition for finishing. What comes next describes the observed results.
    [0071] A stable high definition image has been achieved. The ink appeared to be embedded within the surface of the substrate and this was shown to be the case after examination using a large magnifying microscope. In addition, pieces of leather printed using a forced penetration mechanism did not exhibit degradation or fading. Therefore, the results of printing through forced penetration appear to be highly stable. The ink was dried at the time of a thermal press. However, a similar effect will be observed with the use of a wet paint. In this respect, however, since it is advantageous to achieve a high definition image, you can preferably, in the case of wet ink placement, take steps to reduce the lack of clarity of the printed image. The following describes concepts related to executing the above process, in particular concepts applicable to an industrial leather printing machine.
    [0072] Having established that "forced penetration" yields good results, a commercial process was designed. Preferably, such a process can be one or more of the following: high volume, fast and / or robust; inexpensive; efficiency, for example, low travel / maintenance costs; low print failure rates; easy to use, for example, controls are user friendly; and / or favorable to the environment, for example, reduced impact compared to other finishes. With regard to environmental impact, since the process involves direct printing, toxic chemicals such as acetate, for example, to remove plastic, can be avoided. Similarly, pollutants can be reduced by avoiding the use of solvent-based dyeing.
    [0073] The process can be subdivided into stages, for example: tanning (this may involve providing a chemical treatment to the leather during the tanning process as described in additional details below); pre-press treatment (for example, leather binding and / or supply of retainers as described above); preparation for printing (for example, dehydration, heating to remove the water content and / or reduce changes in dimensions through the subsequent application of heat during printing) and / or cleaning (for example, using ultrasound); coating with the ink acceptor; scan; print; post-printing treatment (for example, reheating or ultraviolet scanning to fix ink to leather, for example, to increase the binding of ink molecules to leather); execution of control software (for example, to determine ink droplet size dependent on a spatial variation of a leather property through the piece of leather to be printed and / or to determine the need for additional leather treatment; for example, additional dehydration treatment (eg heating) to reduce water content).
    [0074] For each stage, there may be several options. For example, dehydration may comprise running leather racks through a dehydration oven with extractors to remove water / steam. The heating preferably continues at a temperature of about 70 ° C until the water content has reduced to about 5% by weight. The time required may vary depending on the size, thickness and tanning method applied to each batch. Cleanliness can be achieved by warm blasting with a mixture of CO2 / warm air jet and / or a light polishing mechanism to remove large or persistent pieces of impurities. In addition, these stages are not necessarily carried out in any particular order, for example, preparation for printing can take place before prepress treatment.
    [0075] The following paragraphs describe the selected device and related processes. Leather can be tanned, for example, with the use of an additive to improve the acceptability of the ink (preferably, stick to the ink) and print quality. The leather is treated (chemically / mechanically) for printing. For example, the leather can be dehydrated, pressed (for example, if the leather was supplied in laminated or folded form), clean or similar. At this stage, the prepared leather may be suitable for storage in this state, preferably in "sandwich piles", that is, with blades that attract impurities between adjacent layers of leather or on a rack that separates layers to reduce transfer of impurities from leather between adjacent layers. Such a rack can be used as a transport mechanism to move piles of leather and / or as a support when dehydrating the leather and / or as a feeder mechanism for a main process / machine line. It is efficient to do as many preparations as possible before the leather enters the actual printing process. This can speed up printing and reduce the risk of print line failure. The in-line printing stage preferably has a conveyor mechanism, for example, roller and / or platform mechanism. Once the leather has entered the actual printing process, final preparation for immediate printing is carried out. This may involve mechanical treatment such as preheating to a favorable temperature. There may be chemical treatment applied, for example, coating the leather surface with an ink acceptor. In general, its purpose is to dry the paint and retain it in place for thinking.
    [0076] Before printing, measurable characteristics that impact print quality are identified. The leather is swept to: (a) measure these characteristics; (b) identify failures; (c) obtain a color profile; and (d) obtain a physical profile (area, format). Features that can be scanned can include any one or more of, for example, liquid content (for example, water, oil or the like), pore concentration, leveling, thickness, color and the like. Gaps that can be swept away can include any one or more of pleats, cuts and scratches, holes, bite marks or the like. A calibrated visual profile can provide a color map of the substrate according to the scan results. Physical measurements may be required for scanning, for example, spectroscopy to detect content, photography to detect color, weight or distance measurements to detect thickness, distance measurements to detect leveling, light transmittivity to detect thickness and / or pore concentration, passed through an ultrasound sensor (for example, to detect water content) and similar. Note that scanning for faults and adjusting the print based on this can reduce wear and tear.
    [0077] The scan can find information based on which the printing parameters (for example, ink droplet size and / or color) can be adjusted to optimize print quality and efficiency. The scan can generate a layered digital profile of the substrate showing the respective layer color, water density and location of any flaws / defects / folds and the like. Through the control software, adjustments can be made to the ink color and volume, as well as temperature, pressure and / or press time control. Front-end image control software preferably highlights problem and fault areas to allow the operator to efficiently place the required image. This can be automated as desired.
    [0078] After a process, as described above, has been carried out, the leather may, therefore, have been tanned and pre-treated in a way to improve print quality and efficiency. From appropriate storage, it preferably entered the printing process aligned and was prepared for printing. This includes applying an ink acceptor base coat. It was additionally and preferably scanned to obtain data for the image and software for machine control. The desired image is placed (by the machine operator or automatically) on the scanned leather profile in the front end software application. This can minimize the impact of failures and maximize the usable area. The ink is then placed between the leather and the press barrier. There are several options, for example: (a) the ink is placed on the prepared substrate; (b) the ink is placed on the barrier; and / or (c) the ink is placed in a carrier such as paper or film or "mesh", for example, a flexible wire mesh and has retainers / retention agent, for example, the mesh threads themselves acting as mechanical paint seals. Advantageously, the option holder (c) is reusable.
    [0079] The ink placement method can be based on known technology, preferably inkjet. However, ink volume (droplet size), ink application temperature and other factors can be controlled in an innovative way, and the printing device components, for example, the print head, can be conventional ( for example, CMYK preferably arranged in parallel as in a conventional wide format printer) or unconventional, that is, selected for the printing processes of this document. Similarly, the ink may be an ink currently available, but preferably it is an ink suitable for forced penetration and designed specifically to perfect the new process, for example, taking into account exclusive characteristics and the organic nature of the substrate, preference for low temperature, pressure and the like.
    [0080] Once the paint has been placed on the prepared substrate, a very thin layer of additive is placed over the entire surface, including areas where there is no paint. This is to achieve a substantially uniform finish with uniform performance over the entire substrate. The additive can be sprayed onto the surface in liquid suspension, dry form (powder) or it can be dispersed as a liquid using a blade. The additive can be very thin (less than 0.0050 mm) and does not interfere with the paint.
    [0081] Once the additive, ink and acceptor layer have been placed between the substrate and the barrier, the substrate is pressed and heated to a selected temperature (ie, predetermined) and / or subjected to a selected pressure for a favorable time. These predetermined conditions are preferably calculated by the software. Impression through forced penetration then occurs. The application of ultrasound can additionally assist the penetration of the paint into the leather. Printing can take place (preferably continuing on a journey on the flat conveyor through the scanner described in this document) on a printing bed. As it enters, the required image can be printed on the prepared surface of the leather through continuous swiping, for example, similar to the printing of wide-format platform. The ink can dry on contact with the prepared leather, for example, if the leather is warm, for example, about 70 ° C (having cooled after engraving in a cylinder if this occurs). During image printing, a sheet, for example, a large flexible sheet that moves across the printing bed, covering the substrate, can be brought in to make contact with the substrate. A strong vacuum can be applied through the base of the printing bed to suck the sheet stuck on the substrate.
    [0082] A heated press slide, for example, operated via hydraulics, can then press on the entire printing bed. The press slider is then in contact with the sheet and not directly with the substrate. Such a sheet can be used to protect the image of the press slide surface. As an alternative to the sheet, non-porous paper or other flexible non-porous material can be used. In this way, the sheet / paper and press cursor form the barrier above. Heat and pressure can be applied for a specified time. These parameters may vary depending on the properties of the substrate (as determined by scanning). For example, for 3 mm (4ftx8ft) vegetable tanning, suitable parameters can be: time: 15 s, pressure: 0.05 MPa (8 psi), temperature: 170 ° C.
    [0083] After printing, the press and sheet cursor are raised and the vacuum is released. The leather can continue along the conveyor and out of the printing bed. Readjusting the printing mechanism for the next piece may involve replacing and / or cleaning the sheet and / or press cursor. The main print engine preferably obtains good print quality and reliability and, preferably, at the same time of maximized speed (for example, operational productivity) and minimized failure rate.
    [0084] Although the process up to that point may have been, in general, on a platform (for preparation and sweeping and perhaps ink placement), thermal press, in particular, can be performed by rollers and / or platform. There is also potentially a need for a vacuum during press. This can: (a) hold the leather in place during press; (b) removing excess water vapor; and / or (c) improve paint penetration by creating a pressure differential. After printing, the leather can be treated mechanically or chemically to: (a) fix the ink; and / or (b) return some of the characteristics (for example, rehydrate). At this point, the leather substantially completed its journey through the process and is now printed and preferably in an improved state (normal temperature, hydration levels, flexibility and the like). You can then continue through a conventional finishing process, for example, grainy embossing, protective coating, water proofing and the like.
    [0085] Advantageously, the process described above can allow high definition printing, color images on the leather surface. Since the acceptor, paint and additive is "injected" into the surface and fixed there (usually by fixing collagen in the leather), it bonds well without the need for additional coatings. The results can be a robust color print, which is permanent and moves with the leather. The process can be industrialized to be driven at high speeds and included in tannery finishing production lines. In all cases above the software above, software may have been provided to perform image / color management and control the entire process. Such software can take into account known variables of leather such as: type, average thickness, average density, average color, average size / dimension, average water content and the like. A sample of a batch to be printed can be pre-tested to establish any combination of these variables. The control software can then adjust print parameters accordingly to optimize print or output quality.
    [0086] Such software can control the processing of raster image (RIP), which can be calibrated so that it takes into account background colors. The type of output can be controlled, for example, if the leather has natural color variations from growth, processing can correct this. The RIP can control not only the color, but the ink density, for example, the droplet size so that stronger coverage can be applied to areas that require the same. Image / color management can include surface failure management. For example, a control screen can highlight areas where there are imperfections. The software can be adjustable to move the pattern / image to better disguise / hide / avoid flaws, for example, to maximize usage.
    [0087] Control code is additionally provided to implement the system described above and control procedures (for example, any of the above software cases), for example, in an embedded processor. The code can be provided on a carrier such as a disc, CD- or DVD-ROM, programmed memory such as read-only memory (Firmware), or on a data carrier such as an optical or electrical signal carrier. The code (and / or data) for deployment can comprise source, object or code executable in a conventional programming language (interpreted or compiled) such as C, or assembly code, code to configure or control an ASIC ( Application Specific Integrated Circuit) or FPGA (Field Programmable Port Arrangement), or code for a hardware description language such as VERILOG or VHDL (Hardware Description Language for very high speed integrated circuit). Such code and / or data can be distributed among a plurality of components coupled in communication with each other.
    [0088] Any of the above descriptions / examples related to printing processes and / or printers can be used to print leather for a variety of applications, for example, shoes, furniture, bags and bags, accessories (gloves, belts, wallets and the like), clothing, automotive area (eg train / aircraft / boat / car seats and the like), interiors, books and office supplies, packaging, riding items and the like.
    [0089] Furthermore, what has been described above can be applied in the same way to printing on non-leather substrates. Undoubtedly, many other effective alternatives will occur to those skilled in the art. It will be understood that this disclosure is not limited to the examples described and covers evident changes to those skilled in the art that are within the spirit and scope of the attached claims.
    权利要求:
    Claims (15)
    [0001]
    1. Apparatus for printing on leather characterized by the fact that it comprises: an ink acceptor applicator that applies an ink acceptor base coating directly on a leather surface; an ink applicator that applies ink to at least one of the ink acceptor and the leather surface; an additive applicator that applies an additive to at least one of the paint acceptor, the paint and the leather surface; a barrier that has a surface configured to contact the acceptor, the paint and the additive on the leather surface; and a heater that heats the barrier surface to one of a predetermined temperature and a temperature within a predetermined temperature range so that the barrier, which is impervious to paint and has a melting point above the predetermined temperature range, enters in contact, at least, with the acceptor, the ink and the additive on the leather surface directly to soften the acceptor, the ink and the additive in the leather and the acceptor, the ink and the additive soften and penetrate the leather.
    [0002]
    2. Apparatus, according to claim 1, characterized by the fact that a lower temperature in the predetermined temperature range is greater than 100 oC.
    [0003]
    3. Apparatus, according to claim 1, characterized by the fact that a higher temperature in the predetermined temperature range is less than 220 oC.
    [0004]
    4. Apparatus, according to claim 1, characterized by the fact that it also comprises a pressurizer that applies pressure directly to the acceptor, the paint and the additive applied by pressing the heated barrier against the acceptor, the paint and the additive to a selected pressure.
    [0005]
    5. Apparatus, according to claim 4, characterized by the fact that the pressure is less than 0.345 MPa (50 psi) and greater than 0 MPa (0 psi).
    [0006]
    6. Apparatus, according to claim 1, characterized by the fact that it is configured to apply the barrier to the acceptor, paint and additive by one of: a period of time within a predetermined period of time, and a predetermined period of time.
    [0007]
    7. Apparatus, according to claim 6, characterized by the fact that the period of time in which the apparatus is configured to apply the barrier to the acceptor, paint and additive is less than or equal to 2 minutes.
    [0008]
    8. Apparatus, according to claim 1, characterized by the fact that it also comprises a heater that dehydrates the leather to make the water in the leather become steam and at least one among: a suction device at vacuum that sucks steam from the leather; and an absorption material that absorbs steam out of the leather.
    [0009]
    9. Apparatus, according to claim 1, characterized by the fact that it also comprises a sweeper that determines a spatial variation of at least one property of the leather, in which at least one property is selected from the group consisting of liquid, protein, fat content, thickness, acidity, pore concentration, leveling, color and surface roughness and where the scanner also detects the flaw (s) in the leather.
    [0010]
    10. Apparatus, according to claim 1, characterized by the fact that it also comprises a printer that comprises an adjuster that adjusts at least one among: total volume of ink applied in a location of the leather, size of a droplet of ink to be deposited on the leather, and color of a droplet of ink to be deposited on the leather, the adjustment depending on a result of determining the spatial variation of at least one property of the leather.
    [0011]
    11. Apparatus according to claim 10, characterized by the fact that the adjuster increases at least one of the ink droplet size and the total volume of ink in a region of the leather that has one of the greatest damage and a water content higher than a region close to the leather.
    [0012]
    12. Apparatus according to claim 1, characterized by the fact that the barrier is configured to retain the paint in a fixed position during an application of heat.
    [0013]
    13. Apparatus according to claim 1, characterized by the fact that it further comprises a computer system comprising: an entrance that inserts the measurements of the surface properties of a piece of leather; an output that outputs the scan results; a data memory that stores the entered measurements; a program memory that stores a processor control code; and a processor coupled to input, output, data memory and program memory that loads and implements the processor control code.
    [0014]
    14. Leather printing method characterized by the fact that it comprises the steps of: applying the base coat of paint acceptor directly on the surface of the leather; apply paint directly to at least one of the acceptor and the leather surface of the leather; apply an additive to at least one of the acceptor, the ink and the leather surface; heating a surface of a barrier that is impermeable to the paint to one of a predetermined temperature and a temperature within a predetermined temperature range; and put the heated barrier that has a melting point above the predetermined temperature range in contact with the ink acceptor, the additive and the ink on the leather surface directly in order to soften the additive, the ink acceptor and the ink on the leather in such a way that the ink penetrates the leather.
    [0015]
    15. Method, according to claim 14, characterized by the fact that it also comprises the mechanical treatment of the leather before an application of the paint to retain the paint in a fixed position during an application of heat.
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    同族专利:
    公开号 | 公开日
    PT3202581T|2019-06-14|
    US8985012B2|2015-03-24|
    ES2632449T3|2017-09-13|
    EP2825387A1|2015-01-21|
    US20130239833A1|2013-09-19|
    JP2015518525A|2015-07-02|
    WO2013135828A1|2013-09-19|
    PL3189973T3|2021-03-08|
    JP6039701B2|2016-12-07|
    PT2825387T|2017-04-24|
    ES2727777T3|2019-10-18|
    EP3202581A3|2017-09-20|
    PT3189973T|2020-09-14|
    EP3189973A2|2017-07-12|
    EP3202581B1|2019-05-08|
    EP3189973B1|2020-08-26|
    ES2818533T3|2021-04-13|
    DK3189973T3|2020-11-30|
    CN104334357B|2016-04-27|
    CN104334357A|2015-02-04|
    EP2825387B1|2017-04-12|
    DK3202581T3|2019-08-05|
    HK1207036A1|2016-01-22|
    EP3189973A3|2017-09-27|
    EP3202581A2|2017-08-09|
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    法律状态:
    2018-12-04| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2020-02-18| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-10-27| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-01-05| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/03/2013, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US201261610531P| true| 2012-03-14|2012-03-14|
    US61/610,531|2012-03-14|
    US13/798,252|US8985012B2|2012-03-14|2013-03-13|Leather printing|
    US13/798,252|2013-03-13|
    PCT/EP2013/055264|WO2013135828A1|2012-03-14|2013-03-14|Leather printing|
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